Saturday, August 31, 2019

The Aravind Eye Hospital, Madurai, India: in Service for Sight

Economics of Organization PATAGONIA Case * Introduction Corporate Social Responsibility (CSR) is a broad-based movement in business that encourages companies to take responsibility for the impact of their activities on customers, employees, communities and the environment. Patagonia is a manufacturer of high quality outdoor and adventure sport clothing. Patagonia have found unambiguous ways to couple their products’ function and the brands environmental values.Their business model raises major sums for environmental causes and their technological innovation reduces the environmental impact of their products. * How Patagonia turned CSR into a competitive advantage  ? One important issue for a balanced management has been the willingness of the company to create a profit business but with the desire to respect the environment. We might think that this commitment to the environment is not an internally competitive advantage because it can raise costs and hurt margins. Indeed en vironmentally-friendly policies are not the most financially savy.This issue is important because Patagonia’s entire brand and business is associated with preserving the environment. However, externally, this gave Patagonia a competitive advantage because of the brand loyalty it developed. For example, Patagonia’s existing customer base rose in median age to approximately 44 years old in 2002. Externally, this proved to be a significant strategic issue because competition brands like Columbia and North Face were able to attract younger demographics, which represented a significant source of future income.The company had a particularly strong commitment to the environment – so much so that the management was placed inside implement a policy of slow growth to promote a business model that is more respectful of the environment. Beyond simply slowing growth, the company has undertaken several initiatives for energy efficiency and recycling center for its customer se rvice and retail. This is show how the company controls its growth and reduces waste. Patagonia's methods also show that a slew of counterintuitive business tips can lead to do good while increasing the bottom line and that this is why they got to where they are today. Is this competitive advantage sustainable? In my mind, CSR is a competitive advantage. Firstly corporate social responsibility helps rise the companies prestige and fame, which implicitly leads to an increase in the sales, protection in times of crisis and therefore a greater competitive advantage. Even if certain actions may affect economic performance on the short term, they will eventually lead to an increase in the corporations’ long-term competitive capacity due to their beneficial effects at society level and to the creation of a favorable external environment.Secondly, we may state that social responsibility is the corporations response to the requirements of the environment, in the sense that the compan ies’ own actions and goals should be linked to the common interests and major tendencies of the reference environment. It also gives a competitive advantage to the corporations themselves, helping them ensure a sustainable development.

Friday, August 30, 2019

National Food Security Bill 2013 Essay

Only three percent of Indians pay income tax; our tax-GDP ratio is among the lowest in the world. This must change. Our elites must realise that India’s poverty has damaging consequences for them, and that they can help decrease it. The food security bill, with all its limitations, will hopefully contribute to generating such awareness, says Praful Bidwai. After vacillating for years over taking any pro-people measures, the United Progressive Alliance finally did something bold and worthy by having the National Food Security Bill passed in Parliament — a promise made in the UPA’s â€Å"first 100 days† agenda after its return to power in 2009. The Bill won a resounding victory in the Lok Sabha, with a margin exceeding 100, because non-UPA parties including the Janata Dal-United, the Dravida Munnetra Kazhagam and even the Shiv Sena felt they had no choice but to support it. It sailed through the Rajya Sabha too. The stage was set by a rare, spirited speech by Congress president Sonia Gandhi, in which she described the legislation as India’s chance to ‘make history’ by abolishing hunger and malnutrition, and emphasised that India cannot afford not to have the law: â€Å"The question is not whether we can [raise the resources] or not. We have to do it.† The NFSB has invested meaning, public purpose and a degree of legitimacy into the UPA’s otherwise corruption-ridden, shoddy and often appalling performance in government under an increasingly right-leaning leadership. This at once put the Bharatiya Janata Party on the defensive. Its leaders were reduced to opposing a measure that represents genuine social progress, and making thoughtless statements about the Bill being about ‘vote security’, not food security. The BJP now has nothing to offer to the nation but obscurantist programmes like building a temple at Ayodhya, and parochial, and predatory pro-corporate agendas under Narendra Modi’s rabidly communal leadership. The Bill is open to the criticism that it doesn’t go far enough. Instead of universalising subsidised food provision, it confines it to two-thirds of the population, and truncates it further by limiting the food quota to five kilos of grain per capita per month instead of the 35 kg per family demanded by right-to-food campaigners. The per capita quota puts small households, such as those headed by widows and single women, at a disadvantage. A universalised Public Distribution System, covering the entire population, has been proved to be more effective and less prone to leakage than one targeted at ‘below-poverty-line’ groups — in Kerala, Tamil Nadu and even poor, backward Chhattisgarh. The relatively well-off won’t stand in queues at ration shops; they select themselves out of a universal PDS. Besides, a large proportion even of those officially defined as poor don’t possess BPL ration cards. The ratio can be as high as 40 percent in some highly deprived states. The latest National Sample Survey reveals that 51 percent of rural people possessing less than one-hundredth of a hectare of land have no ration cards of any kind; less than 23 percent have BPL cards. The problem of identifying the poor remains unresolved. Nevertheless, the broader coverage proposed under the NFSB — and the simple, attractive formula of rice at Rs 3 per kg, wheat at Rs 2, and coarse grains at Re 1 — marks a definite improvement over the current situation. It creates a right or entitlement for the poor, which can go some way in reducing acute hunger. However, right-wing commentators, including neo-liberal economists, credit-rating agencies, multinational and Indian big business, and writers/anchors in the media, have vitriolically attacked the NFSB as an instance of reckless â€Å"populism†. Some claim it will do to little to relieve malnutrition among Indian children, almost one-half of whom suffer from it. Yet others contend that the poor don’t want or deserve subsidies; they aspire to work, earn more and eat better. And almost all of them say the NFSB will entail excessive wasteful expenditure of Rs 1.25 lakh crores. This will aggravate India’s growing fiscal crisis and further depress already faltering GDP growth, now down to four-five percent. Eventually, this will work against the poor. Besides, if investment and growth are to be revived, India can’t spend so much on food security.

Thursday, August 29, 2019

Joan Miro and Dutch Interior Essay

Joan Miro created a surrealist painting, a style that expresses the subconscious using imagery in the subject matter, Dutch Interior shows a man playing the guitar at a table. There are animals and a women sitting around him listening to the beautiful sound. Miro used a wide array of colors especially green and white to emphasize a happy day. He uses complementary colors to allow the colors to clash and have things stand out and be unified from the rest of the canvas. Joan Miro created this painting by observing another painting called The Lute Player. He painted, distorted, simplified and abstracted it by drawing only what he thought was important of the object and using the colors he thought best represented the figure. Miro feels that it is not important to show every little detail because doing that gives your imagination no room to imagine. To him abstracting his images is the best way for him to express his inner feelings. In this painting the Dutch Interior he feels the most i mportant thing is the fact that a man is playing a guitar and so he paints that. He does not think the painting was painted to show the mans velvet hat so he leaves that out. Miro puts a happy warm feeling into his work by painting soft but brilliant colors onto his canvas. He puts soft whites into his painting to emphasize that warm mood of joy. Miro uses the color white also to show important areas of the canvas. Miro also uses some principles of design to try to give this feeling. He uses movement to lead your eye around starting from the man playing the guitar and ending in the lower left hand corner at the place where the dog is sitting. The central focus is the man playing the guitar because he is what the whole painting is basically about. One other important principle of design he uses is asymmetrical balance. There are the same amount of things happening on both sides of the musician. On the left you have a dog starring up at him and listening to the comforting music while on the right side the cat is doing the same thing. Although the central focus is the musician things are happening through out the canvas. Such as out the window there are people sailing boats and inside there are many different animals listening. I get the feeling of a happy day and all is going well and there is nice soft music in the background. The day is calm and nothing can go wrong, everything is just perfect. This painting was painted for the one reason to make people warm and happy inside and to tell people every where that detail is not needed in a painting as long as you have your imagination leading you through it. Miro wants to tell you that there is more to art than recognizable subject matter. You don’t have to know what your looking at.

Wednesday, August 28, 2019

Research Paper #2 Coursework Example | Topics and Well Written Essays - 2250 words

Research Paper #2 - Coursework Example New media platforms such as social media, blogs, digital newspapers, wikis, and websites are becoming more common and widely used in the media industry. Although old media is still trying to remain relevant, new media is exerting increasing pressure on media companies to abandon their traditional media for the new media. According to Dunlop (Para 1), new media is transforming old media by attacking its credibility. This is just one way in which new media is transforming traditional media. With specific regard to print media including newspapers and magazines, the effect is more pronounced. The presence of new media such as blogs, websites, wikis, and social media is rendering the traditional print media less relevant. For instance, even before media companies can print newspapers and magazines with the latest news, the news will have already been featured in the new media platforms. Therefore, by the time the print newspapers and magazines are released, the public has already gotten the news. However, there is still controversy regarding the effect of new media on old media. According to Bernstein (261), despite the new challenges posed by new media, traditional media is not about to be gone soon. This could be right. Currently, traditional media is still relevant. People are still reading print magazines and newspapers. In fact, according to Anderson (Para 1), revenues from digital platforms only account for a small fraction of the total advertising revenues compared to what print newspapers fetch. This shows that traditional print media is still relevant in the digital era. Moreover, the audience for traditional print media has not vanished completely. Although the audience has shrunk significantly, there is still a sizeable audience comprising mainly of the old generations that are not so used to the new media platforms. Even with this raging debate, it is clearly evident that many

Tuesday, August 27, 2019

State Curriculum and Standards for the State of South Carolina Essay

State Curriculum and Standards for the State of South Carolina Compared and Contrasted to the State of North Carolina - Essay Example It is based on a philosophy of teaching and learning that is consistent with current research, exemplary practices, and national standards. In South Carolina "Curriculum standards" has been changed into "Academic standards" came into force in 2004. This is a standards document aims to meet students and their parents expectations. In accordance with the South Carolina Educational Accountability Act of 1998, the purpose of academic standards is to provide the basis for the development of local curricula and statewide assessment. To some entent, these two documents are similar as they stipulate the basic standards nationally accepted. In North Carolina the Standard course of study include: Arts Education, Computer/ Technology Skills, English Language Arts, Guidance, Healthful Living, Information Skills, Mathematics, Second Languages, Science, Social Studies, Workforce Development, Dance and Music Education. The Curriculum of South Carolina include less subject covering only English, Foreign Language, Health and Safety, Mathematics, Physical Education, Science, Social Studies, Visual and Performing Arts fields. So, North and South Carolina have different set of subjects according to their state standards. It should be mentioned that today technological literacy is an integral part of a public school education. Whether or not access to multimedia computers and the Internet are realities for all students, state and national educational establishments, professional organizations and corporations recognize the immediacy of promoting appropriate integration of technology in K-12 classrooms. That is why in both states a particular attention is paid to technology standards for students and teachers which include: woven into curriculum standards, 1 unit of Computer Science required for graduation in South Carolina, and Computer-Technology Skills in North Carolina. For teachers the standards are the same for both state (ISTE foundation standards in State Technology Plan). Both of the states recognize four levels: 1 - Standard level; 2 - Knowledge and Skills level; 3 - Performance Descriptor level; 4 - Grade Level Example. The purpose of the North Carolina Standard Course of Study is to guarantee that all students have equal access to the same basic curriculum. If public education is an avenue to equal opportunity, high standards must be set for all students. The Standard Course of Study does not seek to prescribe how schools should organize themselves or how teachers should instruct. Rather, the curriculum sets standards against which schools and teachers may judge their success. In contrast to South Carolina pays more precise attention to the question how schools should organize themselves in order to help students to achieve their goals. The North Carolina ABCs Accountability Plan establishes performance standards which specify the level of proficiency a student must reach in order to have met specific content standards in specified subject areas. These performance standards are indicators of proficiency for those content areas that are tested. Today, however, the challenge of education is to prepare students for a rapidly changing world. According to standards adopted in South and North Carolina students should be prepared to: compete in a global economy, understand and operate complex communication and information systems,

Optional Essay Example | Topics and Well Written Essays - 500 words - 2

Optional - Essay Example The transistors in the processing chips have continually reduced in size leading to the possibility of measuring them on basis of atomic scale. According to Hagar, 2011, the atomic scale perception of transistors allows QC to deploy quantum mechanics that are governed by wave and relativity laws. While digital computing uses bits, QC uses qubits. A bit represents 0 or 1. A qubit represents 0, 1 and any other superposition possible from the qubit values. This implies that while bits can only contain a particular value, qubits contain a vast amount of values. It is worth noting that QC is capable of undertaking multiple calculations while conventional computing would only partake to one calculation at a time. In addition, QC processes large volumes of data at the same time. It swiftly and accurately solves large relative mathematical problems such as the nondeterministic polynomial (NP) calculations. Chemistry uses the computer to model medicine molecules that are very sophisticated. In order to achieve this, complex calculations (Schrodinger Equation) guide in developing the model structure. The complexity of the medicine structure doubles with each electron added to the basic structure, which is a building block, such that there is a limit past which the conventional computing mechanism is overwhelmed. Currently, computers are only able to model molecular structure not exceeding 300 electrons. Quantum computing can solve SE equations with more than 30 electrons due to its ability to integrate, float and portray basic vast values as mere constitutes to infinite combinations. Systems rely on certain features of data encryption to safeguard sensitive information in banking or transaction activities. RSA is the unbreakable encryption system recognized today because it uses about 300 character integers to encode data. Any attempts to deceiver the encryption require large

Monday, August 26, 2019

JIT variability Essay Example | Topics and Well Written Essays - 500 words

JIT variability - Essay Example Variabilities in production and distribution systems are those unexpected occurrences that upset or alter pre-planned production activities. As a way of overcoming such variabilities, JIT systems use existing inventories judiciously and tactically. For example, â€Å"the 'extra' inventory is then used to cover variations or problems. Effective inventory tactics require 'just in time', not 'just in case'. JIT inventory is the minimum inventory necessary to keep a perfect system running. With JIT inventory, the exact amount of goods arrives at the moment it is needed, not a minute before or a minute after.† (Chapter 16, p.495) One way in which JIT can help remove variability is by â€Å"eliminating inventory that hides variability in the production system†. A suitable analogy to illustrate this point is a lake full of rocks. â€Å"The water in the lake represents inventory flow, and the rocks represent problems such as late deliveries, machine breakdowns, and poor person nel performance. The water level in the lake hides variability and problems. Because inventory hides problems, they are hard to find†. (Chapter 16, p.495) JIT can help reduce variability here by reducing unwanted inventory. The top management can greatly reduce variability by adopting JIT practices.

Sunday, August 25, 2019

Scientific principles and techniques Essay Example | Topics and Well Written Essays - 1500 words

Scientific principles and techniques - Essay Example Mechanics are based on a few laws of nature which are evident without proof or argument. Mechanics is a highly developed branch of physics which is tasked with the determination and description of the motion of bodies and the investigation of the forces that are associated with the motion (Gross, et al. 2009). Suspension system The suspension system of a car is a collection of important systems that are located on the lower part of the car and are part of the chassis. These include the frame, suspension system, steering system and tires and wheels. The suspension of a car is mainly composed of three systems namely springs, dampers and anti-sway bars. Springs are based on four designs: coil springs which are the most common and are made of a heavy-duty bar that is coiled around an axis. They compress and expand when a force is applied on them to absorb the motion of the wheels; leaf springs which are made up of several layers of metal that are bound together to perform as a single uni t. They absorb shock in trucks and heavy-duty automobiles to reduce the force exerted on the wheels; torsion bars which are made of a steel bar that is coiled; and air springs which are made up of a cylindrical chamber of air placed between the wheel and the body of the car. Manufacture The material is commonly used is alloys of steel such as high-carbon, chrome vanadium and stainless steel. The manufacture process of the springs involves coiling, hardening and a final stage of finishing. Leaf springs are made from bars of flat stock and are heated to elevated temperatures. They are then formed by the use of a machine or by hand. Car springs are made by hot winding which involves heating the metal to very high temperatures to make it formable. When red hot, the bar is then coiled around a mandrel until it acquires the required shape then it is quickly removed from the mandrel and dipped in oil to cool and harden it. To ensure the spring acquires the required strength it is heat trea ted appropriately. For the leaf springs, the flat ends are attained by grinding. The bar is mounted in a jig and is held against an abrasive wheel that is rotating until the required flatness is achieved. A coarse wheel is used first then a finer wheel is used to ensure a fine finish and a cooling lubricant is used to ensure a quality finish and to increase tool life. In a subsequent processes, the spring is exposed to bombardment with tiny steel balls that hammer the steel and make it smooth and this ensures that the steel can resist fatigue and cracking after years of use. The spring is then compressed fully in order to achieve the desired pitch and length and this process is sometimes repeated severally. The coating process which is aimed at preventing corrosion of the metal is the next step. The entire surface of the metal is either painted, dipped in liquid rubber or plated with another metal for example chromium or zinc though electroplating. The spring is then tested through various quality control checks to ensure it adheres to the standards. Function They support the weight, absorb and reduce shock and help to maintain contact by the tire on the road surface. 1. Statics. At rest the coil spring is extended with the only force acting on it being the weight of the car. The leaf spring is curved at rest or when no force is acting on it. 2. Strength of materials. The springs in a car are made of a strong heavy-duty bar that is made of steel. This

Saturday, August 24, 2019

Privacy in Biometrics Essay Example | Topics and Well Written Essays - 2000 words

Privacy in Biometrics - Essay Example Although there are various advantages of using biometrics technology, such as its validity and authenticity and its wide-ranging utilization in passports, identity cards, attendance systems, etc. In the field of information technology, biometrics refers to â€Å"those technologies that measure and analyze human characteristics such as DNA, eye retina, irises, fingerprints, voice pattern, facial pattern and hand measurements† (Rouse, 2008). In this paper, the focus will remain on the use of fingerprints as the major characteristics for identifying a person. More importantly, the paper will include discussion and arguments regarding some of the issues that arise due to usage of biometrics publicly (Woodward, 2003, pp. 23-25). Although biometrics has resulted in number of benefits to the organizations in terms of identity management, however, the advancement of this technology and the application of this technology on public level have raised various questions regarding the accur acy of this technology along with privacy and confidentiality of the data that has been one of the major issues related to biometrics. Expansion in the utilization of internet has been one of the foremost reasons that have resulted in greater utilization of biometrics in various parts of the world. Nowadays, biometrics has become one of the most suitable and affordable solution for organizations to identify their employees for identification purpose at entry and exit locations, as well as during attendance on daily basis. At the same time, biometrics has also helped e-commerce industry to progress by ensuring security of data in finance-related organizations such as banks, shopping centers, etc that now use biometrics technology (Zhang, 2006, pp. 31-38) to prevent any fraudulent actions that usually occur in absence of such technologies. One of the basic reasons of huge popularity of biometrics technology has been its use by the law enforcement agencies around the world that has res ulted in its usage on mass level. While this utilization became the reason of its popularity, it has resulted in initiation of debates regarding the confidentiality and security of the data; in other words, data and information management by the law enforcement agencies and various governments globally (Ex-sight, n.d.). Discussion As mentioned earlier in the paper, biometrics while providing enormous number of advantages in terms of identification and verification of individuals in terms of their characteristics, it has resulted in various ethical, social, and professional issues that have been the major focus of this paper. Most importantly, personal privacy is the foremost issue that has remained under debate related to biometrics for a long time. Analysis of literature (Campisi, 2013, pp. 11-17) has indicated that although biometrics technology allows organizations and law enforcement agencies to identify an individual and trace a criminal out of the huge population, it is a dire ct failure to comply with human rights regulations for privacy and anonymity. At various platforms, there have been protests regarding the inappropriate usage of biometric data by law enforcement agencies, which results in an adverse impact on right of freedom of the public. Besides breach of personal privacy, biometrics techno

Friday, August 23, 2019

APA Research Paper on State Standardized Testing for eng 102 class

APA on State Standardized Testing for eng 102 class - Research Paper Example The response to the questions from all the students is given in a consistent way by all the students. The conditions and the procedures for tackling the questions are also consistent among all the students. In addition, the tests provided are often standardized, that is to say they must be according to the education level and knowledge of the students [Moon, Brighton and Hall 2007]. State standardized testing is common in the schools in the US. However, the practice is accompanied by several problems or challenges. One of the challenges or problems caused by the practice is that it results in frustration and resentment among gifted learners in the educational institutions in the US. In most schools in the US, state standardized testing is a common practice. In schools, there are several students with different abilities. Schools comprise of physically challenged children, mentally challenged children, slow learners, medium learners and lastly the special group of gifted learners. Tho ugh there have been a lot of criticisms of the US, the Elementary and Secondary Education Act of 1965 has forced the standardized testing in public schools. Standardized tests are often prepared by very talented people who believe that the level of mastery among all students is the same or similar. These people often prepare the test with the aims of testing the knowledge of a student in a certain subject in relation to the knowledge of other students in the same subject. They also test a student’s strength in a certain paper for example mathematics as compared to the student’s strength in a different paper for example science. However, this comparison of the knowledge levels among different students of the same grade level has resulted in frustrations and resentment among the gifted students as earlier mentioned. Gifted students in institutions are students with good memory, high understanding ability and are therefore fast learners. The standardized tests also do not measure to the quality of education that is always expected of the students, [Popham 1999]. In educational institutions where the standardized testing system is practiced, teachers often concentrate so much on the performance of their institutions. Therefore, they tend to concentrate on all students in the classroom. A class consists of students with different abilities. When a teacher concentrates on all the students at ago, this is a great disadvantage to the gifted learners. First, the pace of learning becomes slow as opposed to the expectations of the gifted learners. The slow learning is due to the other physically challenged children, mentally challenged children and the slow learners present in the same class whose pace of understanding is very slow. The learning system also becomes repetitive because the teachers often prefer to re-emphasize on the weak areas of all the learners as shown by their outcomes or results in the standardized tests. The repetitive learning also is a disadvantage to the gifted learners who prefer fresh and new challenging tasks other than the same old content. The slower pace of learning and the repetitive learning is due to the emphasis on the state standardized testing system and this has at a greater level caused frustration and resentment of the gifted learners in the education institutions in the US. "Standardized tests can't measure initiative, creativity, imagination, conceptual thinking, curiosity, effort, irony, judgment, commitment, nuance, good will, ethical reflection, or a host of

Thursday, August 22, 2019

Why was Ireland Partitioned Essay Example for Free

Why was Ireland Partitioned Essay In the late 19th century, Ulster became the most prosperous province in Ireland, with the only large-scale industrialization in the country. Its linen industry thrived and its products were imported throughout the world. In the latter part of the century, Belfast overtook Dublin as the largest city on the island. Belfast was particularly famous for its huge dockyards owned by Harland and Wolff1. After the famine there was a preponderance of Protestants in Ulster, with a much larger number of skilled workers than the Catholics. Ulster Unionism was and still is composed of two main elements; the protection and preservation of their religion and of the Ulster Economy. When the Home Rule party began introducing reforms such as the Land Act of 1870 Ulster Unionists began to feel threatened. They saw these reforms as the thin edge of a wedge which they feared might damage their interests2. Although there were vast gulfs of difference between them, they were able to unite remarkably well under the common banner of Unionism, a resolve which was strengthened with the start of land agitation in the North. They saw this as a direct attack on all they strove to protect3. In the 1885 elections, the Home Rule party won 17 of the 33 Ulster seats, a development which shocked many Unionism and Gladstone introduced his first Home Rule Bill. While Gladstone prepared an Irish policy, Lord Randolph Churchill prepared for his own visit to Ireland. In February, he wrote, I decided some time ago that if Gladstone went for Home Rule, the Orange card would be the one to play4. Ninety-three of Gladstones own Liberal MPs voted against the bill, and it was defeated. Disturbed at how close to success the Home Rulers had come, there was an influx of new members into the orange order. The Ulster loyalist anti repeal union was also established. They had a conditional loyalty to the crown which means they supported it as long as it did not interfere with their interests5. In 1886 the Belfast anti-Unionist riots damaged the Home Rule cause in the North. Also in that year Queens University became an independent University instead of affiliating to the other British Universities. In this way Unionists first began showing their feelings of self-reliance and autonomy6. The struggle for home rule continued, and Gladstone introduced a second bill in 1893, only to see it defeated in the House of Lords. The Parliament Act of 1911 reduced the peers veto on legislation to a delaying power. At this time there were three strands of Unionism the Ulster Unionism of Craig and the Unionist Council; the Irish Unionists with Edward Carson; and the British Unionism and Bonar Law. The Irish position changed when Carson, M.P., for Trinity College, was invited to lead Ulster Unionists in February, 19107. A meeting was held at Craigavon, Craigs home, to receive the new leader on 23 September, 1911; 100,000 people attended. The meeting marked the beginning of the campaign against the Home Rule Bill of Asquith which was to go before Parliament in 1912. This bill was rejected by the Lords, but became law in 19148. On the 28th September (Ulster Day) the Solemn League and covenant was signed by Unionist men only. This showed their opposition to Home Rule. Some to show their intent signed it with their own blood. In January 1913 the Ulster Volunteer force (UVF) was founded9. Men paraded and drilled with wooden weapons at first. At the end of April 35,000 rifles and 5 million rounds of ammunition were landed at Larne by the Unionists. No moves were made by the army or police to thwart them and this caused much anger amongst Nationalists. Herbert Asquiths policy of wait and see was not doing much for the situation and he failed to realise the intent of the Unionists. It was only in late 1913 that he began to take Ulster opposition seriously. The Curragh mutiny of July 1914 was a blow that showed his complete lack of power over Ulster10. The prospect of Ireland being partitioned began to be considered as a serious option around this time when Lloyd George suggested the temporary exclusion of parts of Ulster. Bonar Law stated that this should be permanent and Carson also refused to compromise. In July 1914 King George, recognising the looming crisis called the Buckingham Palace conference in an effort to make some progress. This conference was attended by Asquith, Lloyd George, Bonar Law, Carson, Craig, Redmond and Dillon11. At the conference Carson immediately stated that he would not consider anything other than partition. The question was the area for exclusion and the time for which it would be excluded. Redmond suggested that each county could be given a plebiscite whether to opt in or out of Home Rule12. Carson disagreed and said Ulster should vote as a block. This was unacceptable to Redmond. Neither side would concede the counties of Tyrone and Fermanagh. It was here that the conference broke down. The original intention of the Unionists was to defeat Home Rule for all Ireland. However, as time went on the idea of partition began to appeal more and more to them13. They began to see the safety from interference it would give them. What had began as a device for killing home rule had become an end in itself. The implementation of Home Rule had to be delayed for the duration of the Great War. A coalition government was set up and both Carson and Redmond were invited to become members. Redmond turned it down. This was to place him at a disadvantage that was to have severe consequences14. Carson accepted his place immediately. Urged by Redmond many nationalists signed up to fight in the war. The Unionists also fought. Both sides suffered terrible casualties notably at the Battle of the Somme. The war also brought with it the chance the Irish republicans had been waiting years for. The old saying Englands difficulty is Irelands opportunity rang clear as they started a Rising on Easter Monday 191615. As William Butler Yates later wrote about the event alls changed, changed utterly. All had changed. After the executions that followed 1916, the Irish people would no longer be happy with Home Rule. Overnight Redmond and the Home Rulers lost much of their power. Lloyd George organised talks in September 191816. He talked to Carson and Redmond separately. Carson was told he could have immediate permanent Home Rule for the six counties whilst he convinced Redmond it would only be a temporary measure until the war ended. The Irish Convention was an assembly called by Lloyd George which sat in Ireland from July 1917 until March 1918 to address the Irish Question. However it did not have much success in resolving the problems. By the end of the war John Redmond was dead, the Irish party was a spent force and Sinn Fein had come to power. Dail Eireann had been set up by the republicans as their own parliament to ignore Westminster. The British Government would have let Home Rule slide was it not for the fact it was still on the books. Walter Long was a British Unionist politician17. From October 1919 onwards, he was largely concerned with Irish affairs, serving as the chair of the cabinets Long Committee on Ireland. The purpose of this committee was to deal with the Irish question. He would only consider a settlement which was in the Unionists favor. In this capacity he saw them first reject the county by county option. Instead it was proposed that there would be two parliaments one in Dublin and one in Belfast. Both were directly answerable to Westminster. This move would give Unionists control over their own destiny18. The British governments official stance was in favor of ultimate unification. The Unionists were first offered nine counties. This was turned down as they feared nine was too big for them to retain full control over. Instead they demanded six counties. The government of Ireland bill was introduced on the 26th of February 192019. It caused much hostility in the border counties and rioting in Belfast between June and September. On 3rd May it came into effect, creating separate home rule governments for Southern Ireland and Northern Ireland, the latter he endowed with wider powers than its southern counterpart. Although in southern and western Ireland, this was soon superseded by the Anglo-Irish Treaty, which gave the new Irish Free State a much greater share of independence. The king opened the new parliament in Ulster in May 192120. In conclusion, this essay has examined the reasons behind the partition question in Ireland and had accessed the causes of this divide in detail. It is ironic that the Unionist people fought so hard and so long against Home Rule just to later adopt it for themselves. 1J. J. Lee, Ireland 1912-1985, pages 9-11 2 Alvin Jackson, Ireland 1798-1998, pages 145 3 D. G. Boyce, Nineteenth Century Ireland, pages 200-201 4 D. G. Boyce, Nineteenth Century Ireland, pages 194-195 5 Pauric Travers, Settlements and Divisions, 116-117 6 Paul Bew, Ideology and the Irish Question: Ulster Unionism and Irish Nationalism 1912-1916 pages 8-9 7 D. G. Boyce, Nineteenth Century Ireland, pages 186-187 8 Michael Laffan, The Partition of Ireland, 1911-1925 9 Pauric Travers, Settlements and Divisions, pages 126-128 10 Alvin Jackson, Ireland 1798-1998, pages 151-153 11 J. J. Lee, Ireland 1912-1985, pages 17-20 12 D. G. Boyce, Nineteenth Century Ireland, pages 200 13 Alvin Jackson, Ireland 1798-1998, pages 156 14 J. J. Lee, Ireland 1912-1985, pages 13-15 15 Pauric Travers, Settlements and Divisions, pages 139-140 16 Pauric Travers, Settlements and Divisions, pages 145 17 J. J. Lee, Ireland 1912-1985, pages 19-20 18 Paul Bew, Ideology and the Irish Question: Ulster Unionism and Irish Nationalism 1912-1916 pages 17 19 Paul Bew, Ideology and the Irish Question: Ulster Unionism and Irish Nationalism 1912-1916 pages 118-119 20 J. J. Lee, Ireland 1912-1985, pages 24-25

Wednesday, August 21, 2019

Arfa Batik Essay Example for Free

Arfa Batik Essay From the backyard of the founders house, our exclusive hand drawn batik is now a multi million ringgit industry with markets as far ranging as Europe and the Middle East. Our batik fashion house or haute couture combines contemporary design and traditional Malay motifs into batik of simple elegance, and are very much sought out by discerning customers from around the world. WHAT WE DO We are involve in various batik production processes from manufacturing from printing, colouring/dyeing, designing and tailoring, wholesaling, exporting to retailing of our batik products. We seek to open a chain of Noor Arfa Batik retail throughout the world through franchising. Noor Arfa is Malaysian’s largest commercial Batek producer. Noor Arfa has built a reputation as the leading manufacturer of superior hand – drawn fashion items and accessories. We also train and develop master craftsmen that consistently produce quality with excellence. We stand out as leader in our industry in the way we have perfected the art of combining distinct colour with classic designs and traditional Malay motives, to create Batek of simple elegance. The Market Noor Arfa Franchise operates in a dynamic and evolving marketplace. Consumers are presented with many options for batik textile and we see a growing interest in fashionable and contemporary batik that address the need to be trendy and yet unique in identity. We find our customers desiring the look that is Malaysian and yet global in application. Noor Arfa addresses this gap in the market by providing a more comprehensive product range that addresses the various needs of the different segment of the market for batik wear and textile. Our customers would also not have to worry about quality as we provide a consistent buying experience with our quality policy which is to produce excellent quality product that satisfy our customer needs. We also believe there are other areas of the market that would benefit from our products which we have not yet targeted. For example we see huge potential in offering our product to the trendy and fashionable young market which is looking for cool and â€Å"in† fashion wear. This is an area of the market that is fully aware of the benefits of self identity and yet contemporary.

Tuesday, August 20, 2019

Prevention of Enzymatic Browning in Fruits and Vegetables

Prevention of Enzymatic Browning in Fruits and Vegetables Polyphenol oxidase (PPO) is known to be a key enzyme in enzymatic browning of fruit, vegetables, beverage and seafood in the food industry. The browning of food causes a great quality loss and economic loss of food products. Inhibition of browning by physical treatments has well been developed and there are a wide range of chemicals can also inhibit enzymatic browning. This article overviews the various chemical inhibitors against enzymatic browning in food. Enzymatic browning is one of the major causes in quality loss of vegetables and fruit, beverage and seafood. It is roughly accounted for over 50 percent losses in fruit [1]. It is very important to control enzymatic browning so as to minimize losses and maintain the economic values of the food products. In animal tissues, melanosis is the process results in the formation of dark pigments. The products of melanosis sometimes cause similar visual perception as spoilage and this would make customers not select these products although they are not harmful and do not influence taste of the food. Browning causes many deleterious changes in the organoleptic and nutritional properties of food products that decrease their market values. However, enzymatic browning is beneficial for some of the food products such as tea, coffee, and cocoa. The consumption of fruits and vegetables has been increased due to the nutritional recommendations for health maintain. As a result, the market values of mi nimally processed fruits and vegetables production increases and this will trigger and encourage research in enzymatic browning. Enzymatic browning definition Cell disruption caused by mechanical injury or temperature changes may lead to physiological disorders or even cell death. This loss of cell integrity results in the decompartmentation of phenolic substrates and enzymes [2]. Polyphenol oxidase (PPO) is a critical enzyme catalyzing the oxidation of endogenous phenolic compounds to form grey or brown colors in the enzymatic browning process. PPO is a term which includes a large number of related copper-containing enzymes, including catechol oxidase, tyrosinase and laccase. In the presence of oxygen, PPO oxidizes mono- and di-phenols to o-quinones. Once the products are formed, they polymerize to form high molecular weight compounds or brown pigments as they are highly reactive. The brownish color could be enhanced when they react with amino acids and proteins [2]. Importance of browning inhibition It is essential to control enzymatic browning in order to reduce the economic loss during fruit and vegetables processing. It is essential to control enzymatic browning for the better development in the food industry. The most common way used for the inhibition of browning is the addition of sulfating agents to inhibit PPO. However, sulfite is a toxic molecule and can react with a variety of humoral and cellular components and can cause toxicity [3]. Due to the adverse health effects caused by sulfites, alternative compounds are investigated for anti-browning properties. The ideal compound would be the one which is effective, does not cause any quality loss (eg. taste, flavor, nutritional values) and toxicity, as well as low cost. Until now, many approaches are available to inhibit enzymatic browning, which include the use of ascorbic acid, sodium chloride, kojic acid, 4-hexylresorcinol etc. Enzyme inhibitors, reducing agents, acidulant agents, chelating agents and complexing agents are the common chemical treatments of antibrowning [4]. In order to have a better control of enzymatic browning, it is important to understand its mechanism of actions, the property of the enzyme, substrates, products and their interactions. Minimizing the negative sides of enzymatic browning can extend the shelf life and increase the market value of the food products. Physical inhibition Physical treatments are one of the common approaches in the control of enzymatic browning in the food industries. Hot-air drying, freeze-drying, canning and bottling are examples of some preventive methods. Browning is enhanced by wounding of plant tissue as it stimulates phenolic biosynthesis, hence minimizing the mechanical damage of fruit and vegetables reduce the degree of browning. Reducing the temperature can slow down the rate of enzymatic browning as enzymes are generally inactive at low temperature. However, color change still occurs at 0oc, hence it is important to allow the crystallization temperature of water to be reached as rapidly as possible [5]. Color change would be blocked during commercial frozen (-18oC). When the temperature rises again, browning starts and the rate will be greater if the cellular structure of the plant tissues is damaged by freezing, peeling and slicing [5]. Heating or blanching is the simplest method to inhibit browning by denaturing the enzyme PPO. Heating temperature and time are crucial to maintain the quality of the food products as heating will affects the texture, taste, flavor and nutritional value of the food. PPO is completely destroyed at 80oC [6], but sufficient time is required for the interior part of the fruit or vegetables to reach such temperature. Blanching the green beans for 3.5 minutes at 82 oC and above, inactivated catalase, lipoxygenase, and polyphenol oxidase activities completely[6]. Protection of the fruit and vegetables from oxygen can prevent enzymatic browning when the plant organs cannot be branched. A variety of methods are used in food industries, including airtight package, partial vacuum and oxygen-poor atmosphere. Chemical inhibition Chemicais are the most commonly used for the control of enzymatic browning, but their use in processed food products is restricted to compounds that are nontoxic, wholesome and that do not adversely affect the quality[7]. Inhibition of enzymatic browning can be achieved by hindering the enzyme or by binding to its active site which lower the PPO activity. Chelating agents which remove the copper prosthetic group from PPO can inhibit enzymatic browning. Removing the substrates is another way to prevent enzymatic browning. Substances which undergo complexation with the phenolic substrate and enzymatic modification of phenols are possible ways to inhibit enzymatic browning. Besides substrate, inhibition targeted toward the products, o-quinones, can also be an approach to control enzymatic browning. Chemical inhibitors of enzymatic browning in food will be discussed in detail in this essay. Polyphenol oxidase Definition PPOs are first discovered in mushrooms by Schoenbein in 1856. They are copper-containing proteins and belong to the group of oxidoreductases. A copper prosthetic group is required for its activity. In the presence of oxygen, polyphenol oxidase catalyses reaction of monophenols to o-diphenols (monophenol oxidase activity). It also oxidises o-diphenols to o-quinones (dipehnol oxidase activity). The enzyme in plants have both mono-and diphenol oxidase activity and the ratio of monophenol to diphenol oxidase activity is usually 1:10 to 1:40. [8]. PPO is present in a wide variety of plants and the activity varies from one organ to another and varies inside an organ, depending on the types of tissues or cells. The role of PPOs in plants is believed to resist the infection of microorganisms and virus and to extreme climatic conditions. PPOs are also in involved the development of dark pigmentation in animals. The biosynthesis of melanin pigments and other polyphenolic compounds which often provide a protective function [1]. Indeed, there are many studies concerning the prevention of melanin formation on the face by inhibiting tyrosinase activity, so as to develop whitening agents for the cosmetic industry. Nomenclature Nomenclature of PPOs is sometimes confusing due to their similarity in nature. Jaenicke and Decker write Probably there is no common tyrosinase: the enzymes found in animals, plants and fungi are different with respect to their sequences, size, glycosylation and activation [9] PPOs must have a dinuclear copper centre, in which type 3 copper is bound to histidine residue in their active sites, and this structure is highly conserved [10]. PPOs are normally classified into three types for the convenient use of the term: Catechol oxidase Catechol oxidase (1,2-benzenediol: oxygen oxidoreductase, EC1.10.3.1) has both monophenol oxidase and diphenol oxidase activity. It is the most common form of PPOs in plants that when people talked about PPOs in food it normally refers to catechol oxidase. Reports on the molecular weight of plant PPO are very diverse and variable and it is estimated the molecular masses of PPOs ranges from 20 to 180kDa [2]. Most of the studies show PPOs have an optimum activity between pH 4 and 7, but some reports show that pH optima varies with the proportions of isoenzymes as well as phenolic substrates used [2]. The optimum temperature of PPOs ranges from 15 to 40 oC and this also depends on the same factors as pH. Tyrosinase Tyrosinase (EC1.14.18.1, monophenol, L-DOPA: oxygen oxidoreductase) refers to as monophenol monooxygenase and corresponds to the same enzymes as EC1.10.3.1 but which always catalyze the hydroxylation of monophenols. In aminals and fungi, PPOs are refered to tyrosinase as L-tyrosine is the major monophenolic substrate. It is very similar to catechol oxidase and sometimes tyrosinase is referred as PPOs. It catalyze two distinct reactions of melanin synthesis: the hydroxylation of tyrosine and the oxidation of 3,4-dihydroxyphenyphenalanine (L-DOPA) to o-dopaquinone. Tyrosinase has been a great concern in humans in the cosmetic industry as it plays a key role in mammalian melanogenesis, which leads to the formation of dark macromolecular pigments, melanin. Laccases Laccase (p-diphenol oxidase, E.C. 1.10.3.2)(DPO), has the unique ability to oxidase p-diphenols into their corresponding quinones, which allows it to be distinguished from catechol oxidase. The enzyme contains many subunits and there are three types of copper centers in each subunit. They occur mainly in fungi and higher plants while much less frequently in the plant kingdom than PPOs. They are glycoproteins with a carbohydrate content of about 15-41% and they have a molecular weight of about 60 to 80 kDa. Substrate Phenolic compounds are substrates for PPOs. There is a wide variety of phenolic compounds found in plants, but only a small number serves as direct substrates for PPOs. Degree of enzymatic browning varies widely from one plant to another. Not only content of PPOs contributes to the variation, quantitative and qualitative aspects of their phenolic content also affect enzymatic browning in fruit and vegetables. In the studies of enzymatic browning in various fruits such as apples, grapes, and peaches, the effects of phenolic content and polyphenol oxidase on the rate of enzymatic browning have been reported [11-13]. Phenolic compounds contain an aromatic ring with one or more hydroxyl groups, together with other substituents. The differences in species, ripening and environmental conditions of growth and storage influence the phenolic composition of plants. Phenolic compounds are essential in fruit and vegetables as they contribute to flavor, color and taste in fruits. Flavonoids are t he major phenolic compounds occurred in plants. Caffeic acid derivatives and monomeric flavan-3-ols often appear to be the best substrates [2]. In some cases, phenolic compounds which are not direct substrates can also take part actively in enzymatic browning by coupled oxidation reaction. Tyrosine, an amino acid, is a monohydroxy phenol and it is an important substrate for PPOs in animals. Caffeic acid derivatives, such as chlorogenic acid, the major diphenolic compounds in plants, act as substrates for polyphenol oxidases. Chlologenic acid is the main substrates for enzymatic browning in apples. On the other hand, some phenolic compounds may also act as inhibitors for PPOs. Apple polyphenol oxidases can be inhibited by various cinnamic acids acting as substrate analogues [1]. Mechanism of action Monophenol oxidase activity for the hydroxylation reaction is normally slower than the oxidation reaction for the production of quinine, which leads to the initiation of the polymerization reaction. Thus it is the rate determining step in the production of brown pigments from monophenols. One mole of oxygen is required for the reaction as shown in Figure 2. When there are only diphenolic substrates, production of the brown pigments will be faster due to their high catalytic rate in the formation of quinines. The primary products, o-quinones, are reactive and unstable compounds, which can undergo further oxidation to brown melanin pigment (figure 3). O-quinones are strong electrophiles which can suffer nucleophilic attack by water, other polyphenols, amino acids and proteins, leading to Michael-type addition products [14-16]. The final products have more intensive color than the o-quinones. Their color depends on the phenol from which they originate. Chemical inhibitors of PPO Plant Polyphenols Polyphenols are a diverse group of compounds having multiple phenolic functionalities [18]. Plants are a rich source of polyphenols which are almost free of harm effects. There are continued investigations of tyrosinase inhibitors from plant extracts, aiming to search what bioactive chemicals in plants have significant inhibitory effect. Flavonoids are one of the most common and best studied groups of plant polyphenols. Flavonoids can be further divided into six subgroups, which are flavanones, isoflavones, flavonols, flavanols, flavones and anthocyanidins. Some flavonoids such as catechin act as substrates for PPO while some of them, eg. quercetin and kaempferol have inhibitory effect on PPO [19, 20]. Isao Kubo studies the inhibition kinetics of kaempferol extracted from saffron flower and it is found that to be a competitive inhibitor, its inhibitory activity presumably comes from its ability to chelate copper in the enzyme [20]. This copper chelation mechanism may be applicable fo r all of the flavonols as long as their 3-hydroxyl group is free [20]. However, 3-o-glycoside derivatives, eg. kaempferol 3-o-glucoside, quercetin 3-o-glucoside, did not inhibit tyrosinase in high concentration [20]. This shows that the free hydroxyl group at C-3 may play an important role in the inhibition. However, some flavones which lack the 3-hydroxyl group, such as luteolin and luteolin-o-glucoside, still have tyrosinase inhibitory effect [21]. (−)-epicatechin 3-O-gallate(ECG), (−)-gallocatechin 3-O-gallate(GCG), and (−)-epigallocatechin 3-O-gallate(EGCG) in tea, especially green tea, are strong inhibitor of tyrosinase and it is found that GCG may act as a competitive inhibitor for the L-tyrosine binding at the active site of the enzyme [22]. It is believed that the flavon-3-ol skeleton with a galloyl moiety at the 3-position is required to inhibit tyrosinase effectively. When the hydrophobicity of gallates increases, the coumpounds are more resistant to be o xidized by tyrosinase as the tertiary structure of the enzyme is disrupted [23]. Structure-Activity Investigations of stilbenes and related 4-substituted resorcinols, obtained from Artocarpus incisus and other plants suggested that the 4-substituted resorcinol skeleton have potent tyrosinase inhibitory ability [24]. Oxyresveratrol, a stilbene isolated from Morus alba, exhibited 32 times inhibitory effect of kojic acid on tyrosinase and the inhibitors act non-competitively on the enzyme [25]. In the structure analysis of extracts from licorice root, glabridin exerts the strongest inhibitory effect on tyrosinase and the inhibitory effect was more effective against monophenol oxidase activity, the rate-determining step, than diphenol oxidase activity [26]. However, glabridins analog, glabrene, was 100-fold less active than glabridine while glyasperin C, isolated from the same part of the plant, was two times more active than glabridin [26, 27]. 6-hydroxydaidzein (6,7,4-trihydroxyisoflavone), one kind of hydroxyisoflavones isolated from soybean koji fermented with As pergillus oryzae, had 6-fold more than kojic acid acting competitively on the tyrosine binding site of the enzyme [28]. It is found that an isoflavone with hydroxyl groups at both the C6 and C7 positions in the A ring would increase both inhibitory effect and affinity to the enzyme more than 10 times [28]. Chalcones, with two aromatic rings in trans configuration, have strong inhibitory effects on tyrosinase. Licochalcone A isolated from the roots of glycyrrhiza species competitively inhibit tyrosinase and the effect was 5.4 times more active than kojic acid [29]. Kuraridin, isolated from Sophora flavescens, was 34 times of the activity of kojic acid in inhibiting monophenolase activity of mushroom tyrosinase [30]. It is believed that the 2,4-dihydroxyl groups in the aromatic ring of chalcone structure was the important substituted group to exert strong tyrosinase inhibitory activity as some simple 4-alkylresorcinols were found to exhibit the strong inhibitory effect [24, 31]. Chelating agents Chelating agents are chemicals that bind to metal ions and remove them from their sphere of action. EDTA (ethylenediaminetetraacetic acid) is a chemical preservative permitted for food industry use. It is a chelator and it is believed that EDTA inhibits PPO activity by either binding to the active copper site of PPO or reduces the availability of copper for the enzyme [7]. the United States Food and Drug Administration approved the use of Calcium disodium EDTA and disodium EDTA to be used as a food additive [32]. EDTA is usually used with other chemicals such as reducing agents (ascorbic acid) and acidulants (citric acid) to prevent enzymatic browning in food. Polyphosphates are another common chelating agent for anti-browning of fresh-peeled fruits and vegetables, but it has low solubility in cold water [7]. Sporix, containing citric acid, ascorbic acid, sodium acid pyrophosphate and calcium chloride, is a powerful chelator and also an acidulant. Browning prevention in apple juice a nd cut surfaces was obtained by Sporix [33]. However, it is not approved in U.S. for food use. Kojic acid (C6H6O4; 5-hydroxy-2-(hydroxymethyl)-4-pyrone), always being use as a standard to compare and study the tyrosinase inhibitory activity of various chemicals in research, is produced by several species of fungi, especially Aspergillus oryzae. Kojic acid possesses both antibacterial and antifungal activities. It is a good chelator and antioxidant that can prevent browning in both plants and seafood. It is commonly found as a food additive and in cosmetic products due to its tyrosinase inhibitory effect. In the phenolic acids tested (caffeic, chlorogenic, cinnamic, coumalic, ferulic, gallic, kojic) for inhibition on PPO, Son et al. reported that kojic acid showed the highest inhibitory activity on apple slice browning [34]. Kojic acid may inhibit the enzyme acting as a reducing agent. If high dose of kojic acid is given to rodents, the level of tyrosine stimulating hormone increases [35]. However, there is inadequate evidence showing that kojic acid would cause cancer in human . Consumption of kojic acid at levels normally found in food does not present a concern for safety [36]. Reducing agent Reducing agents can act as antibrowning agents by reducing the o-quinones back to o-quinones. Ascorbic acid is a good reducing agent and antioxidant which removes oxygen in polyphenol oxidase reactions. As the reaction resulting in the formation of o-quinones is reversible, in the presence of excess reducing agent, o-quinones are reduced to their original o-diphenols. Ascorbic acid is the most widely used antibrowning agent in food due to its reducing property as well as low pH. Since reducing agents act on o-quinones to prevent browning, the effectiveness of ascorbic acids would be decreased if their use is delayed until after the enzymatic reaction has started. In practice, about 0.1-0.3% of ascorbic acid can have protective effect against enzymatic browning. However, one of the drawbacks of ascorbic acid is that it can be oxidized to dehydroascorbic acid irreversibly during the reaction. As a result, it disappears rapidly and browning would occur again upon its depletion (figure 4 ). To overcome its rapid depletion, some derivatives, such as ascorbic acid-2-phosphate (AAP), or ascorbic acid-triphosphate (AATP), are used as substitutes. They are not reducing agents, but when the action of PPO presents they release ascorbic acids. Therefore they will not be oxidized by oxygen rapidly as AAP and AATP can remain stable in the presence of oxygen. Erythorbic acid (EA) has a similar effect and action as Acorbic acid in the inhibiting enzymatic browning. However, it is destroyed at a faster rate than ascorbic acid. Sulphiting agents including sulphur dioxide (SO2) and sulphite are very popular browning inhibitors used in the food industry. It is one of the most effective chemical inhibitors of browning and it is effective even in low concentration. Also, it is inexpensive and hence many food manufacturers use it to inhibit microorganisms growth and enzymes. Sulphur dioxide has three actions to inhibit browning. The first one is its reducing property to reduce o-quinones to its original o-diphenols. The second mechanism involves the formation of colorless products with o-quinones and the last one is that SO2 denatures PPO, resulting in the loss of functionality of the enzyme. Madero and Finne [37] reported that bisulphite could bind to the sulphydryl group at the active site of the enzyme so as to exert competitively inhibit the enzyme. Ferrer et al. [38] proposed that bisulphate inhibited PPO irreversibly by forming sulphoquinones when sulphites react with intermediate quinines, causing complet e inactivation of the enzyme. In addition, it also inhibits non-enzymatic browning that reduces pigmentation of the fruit and vegetables. Sometimes sulphur dioxide treatment is applied before deep-frozen, drying or freeze-drying of fruit and vegetables. In deep-frozen products of apples and apricots, fruit slices are soaked for 3-4 minutes in 0.4-0.5% sulphur dioxide solution. Sulphites are regulatory restricted in food products as it may cause potentially adverse effects on health. There are many reports showing that sulfites are genotoxic in vitro but not in vivo [39]. In the report of the safety evaluation of sulphites as food additives by World Health Organization (WHO), it concluded that when a suitable alternative method of preservation exists, its use should be encouraged, particularly in the applications in the food industry that the use of sulfites is extensive which may lead to its high intake as high level of sulfites in the body may cause life-threatening adverse reactions [39]. Thiol containing (sulfhydryl) compounds are compounds that an oxygen atom in the compound has been replaced by a sulphur atom. Many studies showed these compounds such as cysteine, N-acetyl-L-cysteine and reduced glutathione are able to inhibit enzymatic browning in fruits and vegetables [40]. In this group, cysteine is the most effective anti-browning agent. The proposed mechanism was that it reacted with the quinone intermediates to form stable colorless compounds. The cysteine-quinone adducts are also the competitive inhibitors of PPO. Nicolas et al. showed that cysteine directly inhibits PPO by forming stable complexes with copper [40]. However, use of cysteine is not so encouraged in the food industry because concentration of cysteine used to achieve significant inhibitory effect on PPO would have negative effects on taste. It has also been shown that Maillard reaction products (MRPs) are potential inhibitors enzymatic browning. Amadori rearrangement products, key intermediates in the first states of the Maillard reaction, has chelating, reducing and oxygen-scavenging properties and it might inhibit enzymatic browning [41]. The MRPs derived from glucose with sulfhydryl amino components (cysteine or the tripeptide, glutathione) could be considered as potential natural inhibitors and this was supported by Billuad et al.s study [42]. In a further study conducted by Hesham A. et al., the inhibitory effect of the thiol containing compounds was comparable with 4-hexyl resorcinol and being significantly (p < 0.05) higher than ascorbic acid. The MRPs derived from cysteine/glucose model system were more active than their counterpart derived from cysteine/ribose model system [43]. In a study examining various types of MRPs for their tyrosinese inhibitory effect, monosaccharide-glutathione was more active than glutathione [44]. However, MRPs are unstable and they may negatively affect the sensory quality of the food products as there was unpleasant odor formed from t he apple slices treated with MPRs [44]. Acidulants Most enzymes especially oxidative enzymes activity is very pH-dependent. Extreme pH can denature the enzymes that lead to the loss of the catalytic function. The groups in the active site of the enzymes are ionizable. In the environment of high proton concentration, the structure of the active site may be affected and there may be conformational change that decreases the binding of substrate and catalytic activity. A pH below 3 can effectively inhibit PPO activity [45]. In addition, under extreme pH, substrates may be degraded or change its conformation; as a result, the degraded substrates share the molecular features of the substrates that they may act as enzyme inhibitors [46]. Common acidulants use for PPO inhibition are citric acid, organic acids such as malie, tartaric and malonie acids and inorganic acids such as phosphoric and hydrochloric acids. Citric acid is an acidulants which widely used in the food industry as it is cost effective and highly available. 0.5-2% of it has protective effects against enzymatic browning in fruit and vegetables. The use of 100mmol/L citric acid combined with 10mmol/L glutathione was found to give a great control of browning in litchi fruits and it is recommended this combination can be a good way applied to control litchi fruit quality [47]. Since it is difficult to achieve efficient browning inhibition through pH control solely, citric acid is frequently used in combination with other anti-browning agents, such as ascorbic acid to chelate the copper of the enzyme. However, when the pH is lowered to a level the taste of the food products may be affected and it only can be applied in acidic foods. Complexing agents Complexing agents are able to form complexes with PPO substrates or reaction products, so as to reduce the browning effects. Cyclodextrins and cyclic nonreducing oligosaccharides of six or more D-glucose residues are examples of complexing agents. The hydrophobic central core of cyclodextrins can form inclusion complexes with phenol compounds, leading to the depletion of PPO substrates. Due to the limited space in the core of cyclodextrins, larger guest molecules only partially bind to it and form relatively weak complexes. However, chemical modification of cyclodextrines increases the binding and hence increases the inhibitory effect on PPO. In a study using chlorogenic acid as a substrate to compare ÃŽ ±-, ÃŽ ²- and ÃŽ ³-cyclodextrins in the formation of inclusion complexes, ÃŽ ²-cyclodextrins are more effective in inhibiting browning in apple juice [48]. The internal cavity of ÃŽ ²-Cyclodextrins is non-polar that it induced inclusion complex formation with the phenolic substrates of polyphenol oxidases, preventing them oxidizing to quinones and hence stop the subsequent polymerization to brown pigments. However, complex formation by cyclodextrins is not specific and it may remove the desirable color and flavor compounds of the food product. Cyclodextrins are insoluble in water, so it is better to be used in volatile or insoluble food ingredients in the food industry. The use of cyclodextrins in fruit and vegetable juice are patented, but it have not been approved to use in food by the FDA [49]. Chitosan, a naturally abundant polymer of ÃŽ ²-(1-4)-linked -D-glucosamine, is obtained from the chitin of shellfish. It is widely used in agricultural and horticultural as natural biocontrol and elicitor, water filtration and biomedical. Chitosan is a kind of dietary fibre that have an effect in reducing the absorption of bile salts in the small intestine, hence lowering the blood cholesterol level. It also helps to stop bleeding and has anti-bacterial effects. It is safe and non-toxic, and may even gain health benefits to the body. It has been reported enzymatic browning was inhibited by adding 200 ppm chitosan to Mcintosh apple juice [50]. When 2% of chitosan was treated with shrimp during storage, the incidence of melanosis was reduced [51]. Another study showed that chitosan coating can inhibit enzymatic browning in longan fruits and it can improve shelf life and quality of the fruit [52]. The effect might be due the formation of protective barrier on the surface of the fruit, p reventing the supply of oxygen to PPO. Therefore it is applicable that chitosan can be used in the combination with other agents to control browning and improve quality in fruit and vegetables during post-harvesting and storage. Enzyme inhibitors 4-hexylresorcinol is the one of the most potential PPO inhibitors apply to fresh-cut products. It has obtained the GRAS status for use in the prevention of shrimp melanosis and it proved to be more effective than sulphites in the inhibition of melanosis [7]. Due to its specific mode in the inhibition of enzymatic browning and effectiveness at low concentration, it may be a potential substitute to sulphites. The combination of it with ascorbic acid improved browning control in apple slices [53]. In a study investigating the combination effect of cysteine, kojic acid and 4-hexylresorcinol on the inhibition of enzymatic browning in Amasya apple juice, the interaction of kojic acid and 4-hexylresorcinol was found to have a positive effect on the inhibition of enzymatic browning [54]. Everfresh, a patented product containing 4-hexylresorcinol as the active ingredients and sodium chloride, showed better stability to blackspot formation than sulphites and it is proposed to be use for the in hibition of enzymatic browning in fruit and vegetables [55]. Sodium chloride, or saline water, is widely used in daily life as an anti-browning agent in freshly cut apple. It can also slow the microbial growth in the food products. Its effects on PPO increase when concentration increases. In an experiment examining the effects of salinity on PPO and peroxidase activity, increasing levels of salinity  reduced both oxidases activities immediately after cutting and throughout 7  days of storage [56]. Samples cultivated under high  salinity had also the lowest change in colour and showed the lowest reduction in total phenolic content and antioxidant capacity after 3  days of storage [56]. However, due to its inadequate protective effect at low concentration and unwanted salty flavor at high concentration, its application in the food industry is limited. When it is used with ascorbic acid and acidulants such as citric acid, the inhibitory effect is enhanced and prolonged. However, as the pH is getting higher, the inhibitory effect would dec rease. Its inhibition to PPO might be achieved by interacting with the copper at the active site of the enzyme. Sodium chloride at a concentration of 2-4% is usually used to inhibit browning in the food industry. At 1-2% concentration soaking for less than 1 minute, it can afford temporary protection from surface browning of sliced peeled apples for freezing, or ready-to-use fresh food. Other chemical inhibitors Sodium chlorite is an effective sanitizer inhibiting microbial growth. It can generate chlorine dioxide in acidic environment. Chlorine dioxide is a very powerful oxidizing agent and found to have inhibition in browning reaction. The anti-browning effect of sodium chlorite was gr

The Effects of Child Abuse Essay examples -- Child Abuse Essays

The effects of child abuse are multiple. The pain and trauma the abused child goes through is just a small part of how this cauldron of hidden depravity in our society affects all of us. Wrecked lives can be seen in persons of all ages and in all walks of life. Society as a whole is also effected by child abuse both in negative and positive ways. In this essay I will present some of the factor and results of this violent behavior on individuals as well as our culture. Early American culture did not consider child abuse a crime. Children over the age of 7 were made to work as hard as adults of the time period. They were often beaten if they did not. This changed in the late 19th century when 9 year old Mary Ellen, who endured physical beatings from her foster mother, was reported to the authorities by concerned neighbors who heard Mary’s repeated cries at the hand or switch of her foster mother. In 1874, a mission volunteer named Etta Wheeler was informed of Mary’s cruel life of beatings, imprisonment and cold-hearted servitude. When Etta Wheeler was finally permitted to observe Mary in her living quarters, appalled she began to do everything in her power to get Mary out of her horrid situation. Wheeler convinced the American Society for the Prevention of Cruelty to Animals to intervene and by legal means have Mary removed from the home. Their argument was that â€Å"Mary Ellen was a member of the animal kingdom, and thus could be i ncluded under the laws which protected animals from human cruelty† (Bell, 2011, p. 3). Out of this advocacy for Young Mary was formed the Society for the Prevention of Cruelty to Children. The overall effect of young Mary’s abuse was permanent changes in United States law making abuse, violence, and negle... ...y know about some forms of family violence, such as child abuse, we should be able to more quickly gain a better understanding regarding every type of family violence that we encounter in our society. What we learn about overcoming child abuse, may be helpful in therapy for partner abuse, or elder abuse. The continuing cycle of child abuse can be ended when we are willing to look at the devastation it leaves in the lives of not only the child victims, but everyone who is a part of the family or society where family violence dwells. When individuals are willing to stand up for these young victims and get involved, only then will positive change come. Look at the positive change that grew out of the abuse and rescue of one 9 year old girl named Mary Ellen when one person with compassion in her heart was willing and resolute to get involved and make a difference. The Effects of Child Abuse Essay examples -- Child Abuse Essays The effects of child abuse are multiple. The pain and trauma the abused child goes through is just a small part of how this cauldron of hidden depravity in our society affects all of us. Wrecked lives can be seen in persons of all ages and in all walks of life. Society as a whole is also effected by child abuse both in negative and positive ways. In this essay I will present some of the factor and results of this violent behavior on individuals as well as our culture. Early American culture did not consider child abuse a crime. Children over the age of 7 were made to work as hard as adults of the time period. They were often beaten if they did not. This changed in the late 19th century when 9 year old Mary Ellen, who endured physical beatings from her foster mother, was reported to the authorities by concerned neighbors who heard Mary’s repeated cries at the hand or switch of her foster mother. In 1874, a mission volunteer named Etta Wheeler was informed of Mary’s cruel life of beatings, imprisonment and cold-hearted servitude. When Etta Wheeler was finally permitted to observe Mary in her living quarters, appalled she began to do everything in her power to get Mary out of her horrid situation. Wheeler convinced the American Society for the Prevention of Cruelty to Animals to intervene and by legal means have Mary removed from the home. Their argument was that â€Å"Mary Ellen was a member of the animal kingdom, and thus could be i ncluded under the laws which protected animals from human cruelty† (Bell, 2011, p. 3). Out of this advocacy for Young Mary was formed the Society for the Prevention of Cruelty to Children. The overall effect of young Mary’s abuse was permanent changes in United States law making abuse, violence, and negle... ...y know about some forms of family violence, such as child abuse, we should be able to more quickly gain a better understanding regarding every type of family violence that we encounter in our society. What we learn about overcoming child abuse, may be helpful in therapy for partner abuse, or elder abuse. The continuing cycle of child abuse can be ended when we are willing to look at the devastation it leaves in the lives of not only the child victims, but everyone who is a part of the family or society where family violence dwells. When individuals are willing to stand up for these young victims and get involved, only then will positive change come. Look at the positive change that grew out of the abuse and rescue of one 9 year old girl named Mary Ellen when one person with compassion in her heart was willing and resolute to get involved and make a difference.

Monday, August 19, 2019

Monaural Hearing and Sound Localization :: Biology Biological Hearing Essays

Monaural Hearing and Sound Localization Human hearing and the ability to perceive the location of a sound source has long been accepted as a process requiring the use of two ears (Kistler, 1997; Butler & Humanski, 1992; Carlile, 1990). This process is referred to as binaural hearing. The subjective experience of binaural hearing during the location of a sound source was thought at first to be the result of an interactive process of evaluating two auditory cues (Kistler, 1997; Butler & Humanski, 1992; Carlile, 1990; Middlebrooks & Green, 1991). A man by the name of Lord Raleigh developed a "duplex theory" (Strutt, cited by Carlile, 1990) which stated that sound localization arises out of the fact that the ears are separated by both space and an acoustically opaque mass (the head) that creates two distinctive properties to incoming sounds. First, a sound originating outside the medial vertical plane will reach one ear before it reaches the other creating a time-of-arrival difference that can be detected and used in localizat ion. This process is referred to by Fuzessery, Wenstrup, and Pollak (1990) as an interaural time difference (ITD). Second, the mass of the head causes the incoming sound to lose intensity as it passes from one side of the head to the ear on the opposite side. Fuzessery, Wenstrup, and Pollak (1990) call this process an interaural intensity difference (IID), because the head acts as a muffler. The duplex theory survived until neuroanatomists and neurophysiologists began to search for the biological mechanisms of which the theory attempted to predict (Butler & Humanski, 1992). The duplex theory did prove to be, at least in part, accurate. In 1936 Stevens and Newman (cited by Butler & Humanski, 1992) proved empirically the existence of IIDs and ITDs in locating a sound source. However, they neglected to consider the possibility of other auditory cues that may provide additional localization information. The duplex theory assumed there were no other ways in which the perceptual location of a sound source could be obtained. It was not until much later that the role of the external structures of the ear, namely the pinnae, were considered. According to Butler and Humanski (1992), the role of the pinnae in localizing sound was only taken seriously when scientists began to study sound localization in situations where binaural differences were nonexistent. Some experiments were eventually performed using sound sources which lay directly on the medial vertical plane (referred to as elevation) and did not stray to either horizontal side (Butler & Humanski, 1992; Carlile, 1990; Wightman & Kistler, 1997).

Sunday, August 18, 2019

The Moonstone Essay -- essays research papers fc

Alexandra Lloyd What role did 19th Century popular serial novels such as Wilkie Collins’ The Moonstone play in British understandings of India? When Wilkie Collins first wrote The Moonstone in 1868, it was not published in the form available today, but was published in instalments in a popular Victorian magazine, All the Year Round. Upon its first publication it was eagerly read by the general British public, for its readership not only included the ruling and upper classes, but the cost and availability meant that a copy would have a wide circulation amongst all members of a household. The tale’s images and ideas of India thus reached many social groups in British culture. To Wilkie Collins, the gem, part of whose history we follow in The Moonstone, the novel of the same name, is the signifier of all things that humanity strives for, material and spiritual. He begins the novel by demonstrating that the history of the Moonstone gem is a history of thefts. In having his initial narrator state "that crime brings its own fatality with it" (p.6 Ch. IV of the prologue), Collins underscores the fact that nemesis attends every worldly expropriator of the Moonstone, which to its temporary European possessors is a bauble and a commodity but which to its faithful guardians, the Brahmins, is a sacred artefact beyond price. The Moonstone is never really English or England's, for the novel begins with an account of its various thefts. It opens in India with Rachel Verinder’s Uncle Herncastle's purloining the gem in battle (the opening lines are specifically "written in India"(p.1)) and closes with Murthwaite, the famed fictional explorer's, account (dated 1850) of the restoration of the gleaming "yellow Diamond"(p.466) to the forehead of the Hindu deity of the Moon "after the lapse of eight centuries"(p.466, "The Statement of Mr. Murthwaite"). The date of Murthwaite's account of the restoration of the diamond may be ironic, for in 1850 a Sikh maharajah, exiled from Indian after the Anglo-Sikh War of 1848-9, presented a gem, which is thought to be the ... ...l conciliation and transcendent faith if India were to arise from bloody, mutually destructive, strife and take her rightful place in the society of nations. Today, Collins's The Moonstone may be viewed not as a response to a national insurgency and/or European determination to keep the native in his place, but rather as a love story between two people who only come to see each other for what they are after misjudgements, misunderstandings, accidental and intended deceptions, and considerable self-sacrifice. Bibliography Page references to passages from The Moonstone come from the Oxford University Press, 1999 edition of the novel. Collins, Wilkie. The Moonstone. Oxford, Oxford University Press, 1999. Sutherland, John. â€Å"Introduction and A Note on the Composition† Wilkie Collins’ The Moonstone. Oxford, Oxford University Press, 1999. Stewart, J. I. M. â€Å"A Note on Sources.† Wilkie Collins' The Moonstone. Harmondsworth, Penguin, 1966, rpt. 1973. Pp. 527-8. Fraser, Antonia, ed. The Lives of the Kings and Queens of England. New York, Alfred A. Knopf, 1975. Peters, Catherine. The King of the Inventors: A Life of Wilkie Collins. London, Minerva, 1991.

Saturday, August 17, 2019

Wewewew

Krissy And Ericka — 12:51 lyrics Send â€Å"12:51† Ringtone to Cell Phone Krissy And Ericka 12:51 lyrics was added to the site 1 Feb, 2012 and since that time has 7117 hits and voted 38 times. Other popular Krissy And Ericka lyrics are: Don't Say You Love Me, Up Up Down Down and Change The World. Share Scrolling through my cellphone for the 20th time today Reading that text you sent me again Though I memorized it anyway It was in afternoon in December When it reminded you of the day When we bumped into each other But you didn't say hi cause I looked away And maybe that was the biggest mistake of my lifeAnd maybe I haven't moved on since that night Cause it's 12:51 and I thought my feelings were gone But I'm lying on my bed, thinking of you again And the moon shines so bright, but I gotta dry these tears tonight Cause you're moving on and I'm not that strong to hold on any longer Oh oh oh oh†¦ Then I saw you with her Didn't think you'd find another And my world just seemed to crash Shouldn't have thought that this would last [ Lyrics from: http://www. lyricsty. com/krissy-and-ericka-1251-lyrics. html ] And maybe that was the biggest mistake of my lifeAnd maybe I haven't moved on since that night Cause it's 12:51 and I thought my feelings were gone But I'm lying on my bed, thinking of you again And the moon shines so bright, but I gotta dry these tears tonight Cause you're moving on and I'm not that strong to hold on any longer As the sky outside gets brighter And my eyes begin to tire I'm slowly drowning In memories of him And I know it shouldn't matter As my heart begins to shatter I'm left to wonder Just how it should have been†¦ yeah†¦ 12:51 and I thought my feelings were gone But I'm lying on my bed, I'm not thinking of you againAnd the moon shines so bright, but I gotta dry these tears tonight Cause you're moving on and I'm not that strong to hold on Cause I'll prove you wrong that I can move on through this song So much stronge r The Man Who Can't Be Moved lyrics Songwriters: Frampton, Andrew Marcus; Kipner, Stephen Alan; O Donoghue, Daniel John; Sheehan, Mark Anthony; Going back to the corner where I first saw you Gonna camp in my sleeping bag, I'm not gonna move Got some words on cardboard, got your picture in my hand Saying if you see this girl can you tell her where I am Some try to hand me money, they don't understandI'm not broke I'm just a broken hearted man I know it makes no sense, but what else can I do How can I move on when I've been in love with you ‘Cause if one day you wake up and find that you're missing me And your heart starts to wonder where on this earth I could be Thinking maybe you'll come back here to the place that we'd meet And you'd see me waiting for you on the corner of the street So I'm not moving I'm not moving Policeman says son you can't stay here I said there's someone I'm waiting for if it's a day, a month, a year Gotta stand my ground even if it rains or snows If sh e changes her mind this is the first place she will go Cause if one day you wake up and find that you're missing me And your heart starts to wonder where on this earth I could be Thinking maybe you'll come back here to the place that we'd meet [ From: http://www. elyrics. net/read/s/script-lyrics/the-man-who-can_t-be-moved-lyrics. html ] And you see me waiting for you on the corner of the street So I'm not moving I'm not moving I'm not moving I'm not moving People talk about the guy Who's waiting on a girl, oh whoa There are no holes in his shoes But a big hole in his world Maybe I'll get famous as the man who can't be moved And maybe you won't mean to but you'll see me on the newsAnd you'll come running to the corner ‘Cause you'll know it's just for you I'm the man who can't be moved I'm the man who can't be moved ‘Cause if one day you wake up and find that you're missing me And your heart starts to wonder where on this earth I could be Thinking maybe you'll come back h ere to the place that we meet Oh, you see me waiting for you on a corner of the street So I'm not moving (‘Cause if one day you wake up, find that you're missing me) I'm not moving (And your heart starts to wonder where on this earth I could be) I'm not moving (Thinking maybe you'll come back here to the place that we'd meet) I'm not moving Oh, you see me waiting for you on a corner of the street) Going back to the corner where I first saw you Gonna camp in my sleeping bag, I'm not gonna move Anne Curtis — Tinamaan Ako lyrics Send â€Å"Tinamaan Ako† Ringtone to Cell Phone Anne Curtis Tinamaan Ako lyrics was added to the site 4 Nov, 2011 and since that time has 739 hits and voted 4 times. Other popular Anne Curtis lyrics are: We'll Get There and Sukob Na. Share Nang kita ay makilala Napatulo ang laway ko Binti ko ay nangatog Ako'y sumemplang at nauntog Ewan ko, ano bang meron ka't kikay na to'y napaamo mo? Nabihag mo ang puso kong pihikan, agad na-in love sa'yoIk aw ba ay isang droga at naaadik ako Isang kindat mo lang, mapapa-tumbling na ako Tinamaan na ako Walang hiya ka, Kupido Nasirang schedule ko Putres na kabaliwang ito Lumalaki nang eyebags ko ‘Di makatulog dahil sa'yo Nagmumukhang zombie na ako ‘Di mapakali ano ba ito? [ Lyrics from: http://www. lyricsty. com/anne-curtis-tinamaan-ako-lyrics. html ] Sana lang mapapansin mo rin, Ang kagandahan kong ito Hirap na kasi ang lola mo Nabaliw na ata sa kapapantasya sa'yo Daig mo pa si Pacman, napatumba ako Isang sulyap mo lang, natotorete na ang utak ko Tinamaan na ako Walang hiya ka, Kupido Nasirang schedule ko Putres na kabaliwang itoTinamaan na ako Walang hiya ka, Kupido Nasirang schedule ko Putres na kabaliwan†¦ Tinamaan ako (my papa) Pansinin mo ako (ohh sana) Oras ko'y iyong-iyo (kaloka) Sabihin mo lang sa akin na mahal mo ako, Ililibre ko ang tropa mo Tinamaan na ako Walang hiya ka, Kupido Nasirang schedule ko Putres na kabaliwang ito Tinamaan mo ako Hiling ko, Mr. Kup ido Panain mo rin siya, Nang pagnasaan niya rin ako (La la la, la la, laa†¦ ) Hiling ko, Mr. Kupido (La la la, la la, laa†¦ ) (La la la, la la, laa†¦ ) Hiling ko, Mr. Kupido (La la la, la la, laa†¦ ) Erik Santos Your Love lyrics Send â€Å"Your Love† Ringtone to your CellYou’re the one that never lets me sleep To my mind, down to my soul you touch my lips You’re the one that I can’t wait to see With you here by my side i’m in ecstasy [refrain] I am all alone without you My days are dark without a glimpse of you But you came into my life I feel complete The flowers bloom, my morning shines And I can see [chorus] Your love is like the sun That lights up my whole world I feel the warmth inside Your love is like the river That flows down through my veins I feel the chill inside [ Lyrics from: http://www. lyricsmode. com/lyrics/e/erik_santos/your_love. html ] Every time I hear our music playReminds me of the things that we’ve been through In my mind I can’t believe it’s true But in my heart the reality is you Coz’ I am all alone without you My days are dark without a glimpse of you But you came into my life I feel complete The flowers bloom, my morning shines And I can see Your love is like the sun That lights up my whole world I feel the warmth inside Your love is like the river That flows down through my veins I feel the chill inside Your love is like the sun That lights up my whole world I feel the warmth inside Your love is like the river That flows down through my veins I feel the chill insideYour love is like the sun That lights up my whole world I feel the warmth inside Your love is like the river That flows down through my veins I feel the chill inside MGA MAKABAGONG BANAT LINES! * I am an ASSIGNMENT. Wanna take me HOME?! * Why love a person who just makes you breakfast? When you can love me and be your breakfast! * Pimple ka ba?! Kasi kapag pinipilit kitang tanggalin, nasasa ktan ako†¦ * Girl: Aanhin mo yung hagdan? Boy: Aakyat sana ako sayo ng ligaw Girl: Di na kelangan! Yumuko ka nlang. Boy: Huh?! Bakit? Girl: Pakipulot ung puso ko, nahulog na kasi sayo! * Hangga't andito ako sa mundo,Huwag mong isipin na THE BEST na ang syota mo! * Pwede bang MCDO na lang itawag ko sayo?! Maxado kasing obvious kapag sinabi kong†¦ â€Å"LOVE KO ‘TO!!! † * Girl: Tikman mo tong cake. Masarap. Gawa kasi ng nanay ko. Boy: Ikaw nalang titikman ko. Gawa ka rin naman ng nanay mo eh! * Hi†¦ Hmmm†¦ Sabi ng doctor malala na daw yung sakit ko sa puso†¦ Dalawa na lang daw options ko. Either ICU or U C Me†¦ * Boy: May gagawin ka ba bukas? Girl: Wala naman. Bakit? Boy: Tara, Pakasal tayo†¦ * Boy: Miss, musician ka ba? Girl: Bakit? Boy: Pinapataas mo kasi nota ko eh†¦ * Kapag feeling mo may kulang sa buhay mo†¦ Isipin mong mabuti kung ano†¦ aka†¦ AKO na yon†¦ * If you're nice, you can call me â€Å"baby† If you're sweet, you can call me â€Å"honey† If you're hot, you can call me†¦ tonight! * Sabi ng teacher ko kelangan ko raw ulit magaral ng alphabet. Kasi everytime I recite it†¦ I always miss â€Å"U†Ã¢â‚¬ ¦ * Sana naging camera na lang ako, Para sa tuwing titingin ako sayo, ngingitian mo ko†¦ * Kung may nagtanong sayo na: â€Å"kumain ka na ba? † Ang pinaka nice na sagot dyan ay†¦ â€Å"di pa eh, gusto ko kasi matikman ka muna! † * Sana naging damit na lang ako†¦ Para kahit minsan.. Itry mo kung bagay ako sayo†¦ * My wish is to take off ur clothes kahit 1 beses lang†¦ just wanna know how angels hide their wings†¦ * Anong oras na? †¦ Para masulat ko sa diary ko kung anong oras ako na in-love sayo†¦ † * If you're given a chance to love somebody†¦ Why don't you try me?!?! * Boy: Miss, pwede ba tayong maglaro? kahit ano laro ok lang, wag lng taguan. Girl: Bakit ayaw mo ng taguan? Boy: Because a girl like you is impossible to find†¦ * Boy: Excuse me, May I see the tag of your shirt?! Girl: Why? Boy: I just wanna see if you were â€Å"Made For Me† * Miss, naturukan ka ba ng anesthesia? Bakit di mo maramdamang mahal kita? * Nurse, CPR mo nga ako, coz you're taking my breath away. Paki-auscultate nga yung apical part ng thorax ko†¦ And hear how my heart beats for you†¦ * Miss, let me take your temperature†¦ Coz I think you're hot! * I don't speak french†¦ But I know how to kiss that way†¦ * Kung ako'y pamasahe, ikaw naman ay gasolina†¦ Alam mo kung bakit? Ikaw kasi ang dahilan kung bakit ako nagmamahal†¦ * Super steady ka naman dyan†¦ Galawin kaya kita†¦ * Boy: Buti na lang walang MMDA dito noh†¦ Girl : Bakit? Ano nangyari? Boy: Nagkabanggaan puso natin eh†¦ * Buti pa ang cholesterol†¦ may lugar dyan sa puso mo†¦ * Pag ako yumaman, magtatayo ako ng grocery store at mura lng bilihin†¦ .. Dahil say o lng ako magmamahal†¦ * Aabsent na ako sa lahat ng klase ko†¦ Makapasok lang ako sa PUSO mo†¦ * Question lang†¦ Can you recommend a good bank where i can make a deposit? Kasi†¦ Im planning to save all my love for you†¦ * Boy: Idedelete na kita sa friendster ha†¦ Girl: Bakit? Boy: Ayoko kasi ng friends lng eh†¦ * Boy: Sana pinto ka na lang? Girl: Hay naku! Bakit nanaman? Boy: Para pwede kitang pasukan at labasan†¦ * Grabe na talaga mga banat ngayon noh? Sa sobrang dami wala na akong maisip†¦ kundi IKAW†¦ ****************** * Boy: Miss, para kang sembreak†¦ Girl: Hay naku, Banat nnman†¦Aber bakit? Boy: Amboring mo eh†¦!!! * Boy: Alam mo para kang bisyo†¦ Girl: Hihi†¦ Dahil ba hindi mo ko maiwasan? Boy: Hindi. Sinisira mo kasi buhay ko!!! * Girl: Alam mo para kang shades†¦ Boy: .. Bakit naman? Kasi bagay ako sayo? Girl: Hindi! Kasi nagdidilim ang paningin ko pag nakikita kita!!! * Kapag may nagsabi sa yo na di ka magaling manamit at magbihis†¦ Sumagot ka: â€Å"Alam ko! Pero magaling ako maghubad!!! * Kunwary dictionary ako†¦ Sigurado kahit saang page mo tingnan†¦ Hindi mo ako mahahanap†¦ Wala naman kasi akong meaning sayo! * Ang pagmamahal ko sa kanya ay parang paborito kong pagkain†¦ UBOS NA!!! Girl: May bagong unlimited ah? Boy: Oh? Nu naman unli un? Girl: Ikaw, unlimited ka sa puso ko! Boy: Wow ha! talaga? Girl: OO! BUKAS EXPIRED KNA!!! * Banat ng bitter na ex: â€Å"So what kung may chemistry kayo? Bukod sa may history tayo†¦ I know your anatomy†¦ † I just got out of a two year relationship with my boyfriend a few months ago, and I'm just looking for some GOOD quotes about moving on, letting go, or just not needing somebody anymore. Anybody have any? * 3 years ago * Report Abuse Additional Details Something like†¦ Sometimes giving up doesn't mean you're weak; it just means you're strong enough to let go. years ago Key Best Answ er – Chosen by Asker â€Å"There are things that we never want to let go of, people we never want to leave behind. But keep in mind that letting go isn’t the end of the world; it’s the beginning of a new life. † â€Å"We find by losing. We hold fast by letting go. We become something new by ceasing to be something old. † â€Å"In the end these things matter most: How well did you love? How fully did you love? How deeply did you learn to let go? † â€Å"Trying creates impossibilities, letting go creates what is desired. † â€Å"We must learn to let go, to give up, to make room for the things we have prayed for and desired. â€Å"We must be willing to let go of the life we have planned, so as to accept the life that is waiting for us. † â€Å"Letting go doesn't mean we don't care. Letting go doesn't mean we shut down. Letting go means we stop trying to force outcomes and make people behave. It means we give up resistance to the way things are, for the moment. It means we stop trying to do the impossible–controlling that which we cannot–and instead, focus on what is possible–which usually means taking care of ourselves. And we do this in gentleness, kindness, and love, as much as possible. † P. S. Hope this helps! Let me know if you need more!Source(s): http://www. livinglifefully. com/lettinggo. htm * 3 years ago * Report Abuse * 1 person rated this as good Asker's Rating: Asker's Comment: Thanks guys! Other Answers (10) * Terri D . here a few †¦ â€Å"One day I just realized he was gone for good — and it was okay† â€Å"Word of advice, if you have to work this hard, its not working. † The O. C. â€Å"Stop trying to change yourself for a relationship that's not meant to be. † —Sex and the City â€Å"You're right; I'm not who I once was, because we aren't who we once were† â€Å"I never asked for it to be over. Then again, I never a sked for it to begin.That's the way it is with life, some of the most beautiful days come completely by chance; but even the most beautiful days have their sunsets. † â€Å"Do you know that feeling of being completely indifferent? So much that it hurt? So much that it makes you bitter? I guess you wouldn't know unless you've experienced it. It's that feeling of being totally stuck, not knowing what to do or where to go from here. It's painful and it hurts, but one day, you'll wake up, and that feeling will be completely gone, and even though you'll have to start from square one, the pain begins to fade, and you realize you're not hurting that much anymore. * 3 years ago * Report Abuse * 1 person rated this as good * EJ Addy The one song I love (that has some great quotes in the lyrics) for that feeling is â€Å"I'm Moving On† by Rascal Flatts. I'm movin' on At last I can see life has been patiently waiting for me And I know there's no guarantees, but I'm not alone Ther e comes a time in everyone's life When all you can see are the years passing by And I have made up my mind that those days are gone Hope this helps! * 3 years ago * Report Abuse * trina People have a hard time letting go of their suffering. Out of a fear of the unknown, they prefer suffering that is familiar. -Thich Nhat HanhLetting go doesn't mean we don't care. Letting go doesn't mean we shut down. Letting go means we stop trying to force outcomes and make people behave. It means we give up resistance to the way things are, for the moment. It means we stop trying to do the impossible–controlling that which we cannot–and instead, focus on what is possible–which usually means taking care of ourselves. And we do this in gentleness, kindness, and love, as much as possible. -Melody Beattie Source(s): http://www. movingonquotes. net/ www. movingonquotes. net/move-on-quotes. †¦ * 3 years ago * Report Abuse * lola banoi â€Å"Scar tissue is stronger than regular tissue.Realize the strength, move on. † – Henry Rollins Take a second out to think about this: in your life you search and search for the right person for you. Every time you break up with someone you get one step closer to that person. You should look at moving on as getting closer to meeting the one. – Ian Philpot We must be willing to let go of the life we have planned, so as to accept the life that is waiting for us. – Joseph Campbell There are lots on this site. I went there after I broke up with my Boyfriend and found them really helpful. Also, I am quite happy on my own now! So keep smiling hun, and the storm will pass.Source(s): http://www. movingonquotes. net/ * 3 years ago * Report Abuse * Jo W â€Å"When we become aware that we do not have to escape our pains, but that we can mobilize them into a common search for life, those very pains are transformed from expressions of despair into signs of hope† – Henri Nouwen â€Å"Recession is like Failure, it is an Event not a Person, so Just Move on† – Mina Tadros â€Å"She will chase you around for a while but there gonna be one day when she gets tried of running and she gonna move on. At that moment you are going to wish you had let her catch you. † – savannah inman â€Å"I've been over there before.We have to move on. You can't always live in the past of what we did or what we were and I moved on. † – Maurice Cheeks â€Å"I think it's great. You know, just putting the past behind us, just move on. We had three great years together. It was good for us to be able to put this behind us and move on. † – Kobe Bryant â€Å"This is not something you just sort of go, oh, got carjacked and shot, all right, move on–you don't just move on. † – Elizabeth Vargas â€Å"So never let go of something good. Never let go of something you love. For you may may not find another reason above to try adn find t he reason for it inside† – shelby dawson Can one ever let go of the past when the future becomes the present and the present becomes your past? † – TERESA MORGAN â€Å"let go' for i am ready to see life at its fullest and live to the best of myself, and for that reason i am now spontaneous,happy and feel whole. † – nicole gilbert â€Å"If you want a taste of heaven, you have to let go of everthing† – James Dowler Gow â€Å"When you learn to love, you also need to learn how to let go. † – Rodel Natividad Casio â€Å"Hurt is just a reflection of our selfishness. The getting hurt you feel, the more selfish you are. Try to let go is the right antidote. † – Lenny Hidayat Source(s): ttp://www. quotesdaddy. com/quote/609191/†¦ http://www. quotesdaddy. com/find/quote/mo†¦ http://www. quotesdaddy. com/find/quote/mo†¦ http://www. quotesdaddy. com/find/quote/le†¦ * 3 years ago * Report Abuse * Happy Feet â€Å"Sometimes you have to let someone go to see if there is anything worth holding on to. † â€Å"Moving on is simple, it's what you leave behind that's hard. † â€Å"If you love something, let it go. If it comes back to you, its yours forever. If it dosent, then it was never meant to be. † â€Å"Relationships are like glass. Sometimes it is better to leave them broken than try to hurt yourself putting it back together. * 3 years ago * Report Abuse * *Blind Snooker Shot (Angel) © Life is like riding a bicycle. To keep your balance you must keep moving. Albert Einstein To move freely you must be deeply rooted. Bella Lewitsky Those who do not move, do not notice their chains. Rosa Luxemburg Moving on, is a simple thing, what it leaves behind is hard. Dave Mustaine Sometimes the cards we are dealt are not always fair. However you must keep smiling & moving on. Tom Jackson To be able to move on, one has to learn to forgive not only the person (or pe ople) who have done one wrong but also oneself.Eugenia Tripputi Life is about making the right decisions and moving on. Josh Forgiveness and letting go are steps on our road back to happiness. Tina Dayton Courage is not the absence of fear, but simply moving on with dignity despite that fear. Pat Riley If someone you love hurts you cry a river, build a bridge, and get over it. Unknown Don't cry for a man who's left you, the next one may fall for your smile. Mae West More from other Sites: http://thinkexist. com/quotes/like/moving†¦ http://www. aimgirl. com/talk/index. php? sh†¦ Have a nice day! 🙂 * 3 years ago * Report Abuse * Jonathan HuieThe darkest night is often the bridge to the brightest tomorrow. – Jonathan Lockwood Huie Courage doesn't always roar. Sometimes courage is the quiet voice at the end of the day saying, â€Å"I will try again tomorrow. † – Mary Anne Radmacher You are never too old to set another goal or to dream a new dream. – C. S. Lewis The greatest glory in living lies not in never falling, but in rising every time we fall. – Nelson Mandela Celebrate endings – for they precede new beginnings. – Jonathan Lockwood Huie Courage is the power to let go of the familiar. – Raymond Lindquist Success consists of going from failure to failure without loss of enthusiasm. Winston Churchill Fall seven times, stand up eight. – Japanese Proverb Discontent is the first necessity of progress. – Thomas Edison My Mama always said you've got to put the past behind you before you can move on. – the movie Forest Gump Every wall is a door. – Ralph Waldo Emerson We must be willing to get rid of the life we've planned, so as to have the life that is waiting for us. The old skin has to be shed before the new one can come. – Joseph Campbell Source(s): http://www. dreamthisday. com/starting-ove†¦ * 3 years ago * Report Abuse * Kai â€Å"Change is never easy. You fight to hold on.You fight to let go. † â€Å"Growing up is never easy. You hold on to things that were. You wonder what's to come. But that night, I think we knew it was time to let go of what had been, and look ahead to what would be. Other days. New days. Days to come. The thing is, we didn't have to hate each other for getting older. We just had to forgive ourselves†¦ for growing up. † â€Å"Over the course of the average lifetime you meet a lot of people. Some of them stick with you through thick and thin. Some weave their way through your life and disappear forever. But once in a while someone comes along who earns a